Not many people would say they surf the internet. A lot of people would say that they surf the web. They both mean the same, but web is far more popular. And its not just surfing. We tend to explore, post to, chat and even get lost on the web to name a few. For many the internet is the web, and the .WEB TLD will bring these two terms together.
When can I get my .WEB?
The new gTLD applications are still being reviewed. The earliest you can expect for any of the new gTLDs to be available is in the spring of 2013.